Synthesis and Some Reactions of the Metal Phosphorus Double-bonded Complexes C5R5 (CO)2Mo=P(NMe2)2 |
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| Authors: | S Amann K Jörg W Malisch |
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| Institution: | Institut für Anorganische Chemie der Universit?t Würzburg , Am Hubland, D-8700 , Würzburg , W. Germany |
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| Abstract: | Abstract The reaction of the metalhydrides C5R5(CO)3Mo-H (R=H (la), Me (lb) with P(NMe2)3 leads to the metal-phosphorus double-bonded species 2a,b via the intermediate formation of C5(CO)2 (Me2N)3P)Mo-H, which can only be identified spec-troscopically in solution. |
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