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Preparation,structures, and reactivities of compounds with double bonding between the heavier group 5A elements
Authors:Alan H. Cowley  Jan E. Kilduff  Jonathan G. Lasch  Sushil K. Mehrotra  Nicholas C. Norman  Marek Pakulski
Affiliation:Department of Chemistry , University of Texas at Austin , Austin, Texas, 78712, U.S.A.
Abstract:Abstract

The synthesis of diphosphenes (RP[dbnd]PR′), phosphaarsenes (RPxydAsR′), phosphastibenes (RP[dbnd]SbR′), and diarsenes (RAs[dbnd]AsR′) is discussed. X-ray crystallographic studies have been performed on representative double-bonded compounds. The reactivities and coordination chemistry of selected compounds have been explored.
Keywords:
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