|
|||||
|
|
Chiral and Diastereoisomeric Ferrio Phosphanes |
|
| Authors: | Martin Märkl Achim Kaul Wolfgang Malisch |
| Affiliation: | Institut für Anorgan. Chemie der Universit?t Würzburg , Am Hubland, D-8700, Würzburg , Germany |
| Abstract: | Abstract Deprotonation of the iron salts [Cp(CO)2FePRH2] BF4 (R=alkyl, aryl) (1) yields the ferrio-phosphanes Cp(CO)2FeP(R)H (2), which are converted in the presence of PMe3 to the dia-stereomeric derivates Cp(CO)(PMe3)FeP(R)H (3). |
| Keywords: | |