THE B.A.S.I.C. (BINO-ANSA-SPIRO-IN-CYCLOPHOSPHAZENES) SYSTEM. PART I: NEW DERIVATIVES OF THE BIS-(TETRACHLORO-CYCLOTRIPHOSPHAZENYL)-SPERMINE |
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Authors: | Michèle Willson Louis Lafaille Lionel Vidaud Jean-François Labarre |
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Institution: | 1. Laboratoire des Hétérocycles du Phosphore et de l'Azote , Université Paul Sabatier , 118, Route de Narbonne, 31062, Toulouse Cedex, France;2. Laboratoire Structure et Vie , Université Paul Sabatier , 118, Route de Narbonne, 31062, Toulouse Cedex, France |
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Abstract: | Abstract The synthesis of new derivatives of bis-(tetrachlorocyclotriphosphazenyl)-spermine was achieved upon reaction of some MONOSPIRO–N3P3Cl4HN–(CH2) n –NH] (n = 2,3,4) derivatives and of the gem–N3P3Az2Cl4 with spermine. All compounds were obtained in the monomeric state. 31P and 13C high-resolution NMR were used, together with IR spectroscopy and mass spectrometry, to assign molecular structures and to reveal conformational equilibria, if any. |
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