Reaction of Dithiophosphoric Acid Chloride Betaine with Bifunctional Compounds - A New Route to Cyclic Dithiophosphates |
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| Authors: | Manfred Meisel Christiane Donath |
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| Institution: | Zentralinstitut für anorganische Chemie der Akademie der Wissenschaften der DDR , DDR - 1199, Berlin, Rudower Chaussee |
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| Abstract: | Abstract Dithiophosphoric acid chloride pyrididium betaine, Py. PS2Cl (1)1, can be widely used for the synthesis of various organophosphorus compounds. 1 reacts in the presence of a base with an excess of nucleophiles like amines, alcohols or thiols to the corresponding disubstituted thiophosphoric acid derivatives2–3. |
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| Keywords: | Metal complexes clathrochelate phosphorylation phase transfer catalysis X-ray crystallography |
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