Synthesis of S-Sulfonyl-Phosphinothioates and Phosphinodithioates,a Novel Organophosphorus-sulphur Structure |
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| Authors: | Wojciech Dabkowski Andrzej Łopusiński Jan Michalski Czesłw Radziejewski |
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| Institution: | Centre of Molecular and Macromolecular Studies, Polish Academy of Sciences , Boczna 5, 90-362, Lodz, Poland |
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| Abstract: | Abstract Racemic and optically active S-sulphonylphosphinothioates R-SO2-S-P(O)Bu'Ph and dithioates R-SO2-S-P(S)Bu'Ph (R dbnd] Me, p-tolyl) have been prepared for the first time by the reaction of the corresponding acids Bu'PhP(S)SH (X dbnd] O,S) of their salts with sulphonylating reagents RSO2-Y (Y dbnd] Cl, O-SO2R, triazolide). |
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