Synthesis of S,O-Diesterified Dithiophosphate Ion and it's X-Ray Crystal Structure as the N,N-Dipropylammonium Salt |
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| Authors: | Zbigniew Ciunik Jadwiga Jasinska |
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| Institution: | 1. Institute of Chemistry, University of Wroclaw , 50-383, Wroclaw , Poland;2. Institute of Chemistry, University of Gdansk , 80-982, Gdansk , Poland |
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| Abstract: | Abstract Elimination of one methyl group by excess of N,N-dipropylamine transformed S-(3,4,6-tri-O-acetyl-2-deoxy-α-D-glucopyranosyl)-O,O-dimethyl-dithiophosphate1 into the N,N-dipropylammonium (R)S- (3,4,6-tri-O-acetyl-2-deoxy-α-D-glucopyranosyl)-O-methyl-dithiophosphate with chiral centre on phosphorus atom. |
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