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DYNAMIC STEREOCHEMISTRY OF SYMMETRICALLY BUT DIFFERENTLY SUBSTITUTED DIPHOSPHANES
Authors:Rolf Appel  Bruno Brück  Falk Knoch  Johannes Hünerbein
Affiliation:Anorganisch-Chemisches Institut der Universit?t , Gerhard-Domagk-Str. 1, 5300, Bonn 1, FRG
Abstract:Abstract

The main interest of our work in Bonn during the last years was in the field of phosphorus-carbon compounds with multiple bonds. Beside the synthesis of new classes of compounds we were particularly interested in the amazing analogy between the PC- and the CC-double bond, which could be proved by evidence of E/Z isomers and a clear indication of pericyclic reactions.
Keywords:Proton inventory  sulphite ester hydrolysis.
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