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Diastereoselective Coordination of Chiral Phosphine Substituted Thioamide Ligands |
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| Authors: | R Burghardt V Kruppa U Kunze |
| Institution: | Institut für Anorganische Chemie der Universit?t Tübingen , D-7400, Tübingen , F.R. Germany |
| Abstract: | Abstract Homochiral thioamides are forming diastereomeric molybdenum and tungsten complexes in different ways (type 1–3) and different stereoselectivities (1 and 2: > 99%de, 3:0%de). The dissolved complexes 1 epimerized slowly at room-temperature. |
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