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Reactions of Phosphorus-Phosphorus Bonded Mixed-Valence Diphosphorus Compounds
Authors:Gerhard Bettermann  Petra Look  Dietmar Schomburg  Reinhard Schmutzler
Affiliation:1. Institut für Anorganische und Analytische Chemie der Technischen Universit?t , Hagenring 30, 3300, Braunschweig, Federal Republic of Germany;2. Gesellschaft für Biotechnologische Forschung mbH. , Mascheroder Weg 1, 3300, St?ckheim-Braunschweig, Federal Republic of Germany
Abstract:Abstract

A novel type of mixed valence diphosphorus compound, involving the grouping Cl-P(-)-P(+)-NEt2, with the two phosphorus atoms doubly bridged by N.N'-dimethylurea, has become readily available. Reactions of this type of compound have furnished a variety of new structural elements, involving two directly bonded phosphorus atoms in two different oxidation states and / or coordination numbers.
Keywords:
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