Reactions of Phosphorus-Phosphorus Bonded Mixed-Valence Diphosphorus Compounds |
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Authors: | Gerhard Bettermann Petra Look Dietmar Schomburg Reinhard Schmutzler |
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Affiliation: | 1. Institut für Anorganische und Analytische Chemie der Technischen Universit?t , Hagenring 30, 3300, Braunschweig, Federal Republic of Germany;2. Gesellschaft für Biotechnologische Forschung mbH. , Mascheroder Weg 1, 3300, St?ckheim-Braunschweig, Federal Republic of Germany |
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Abstract: | Abstract A novel type of mixed valence diphosphorus compound, involving the grouping Cl-P(-)-P(+)-NEt2, with the two phosphorus atoms doubly bridged by N.N'-dimethylurea, has become readily available. Reactions of this type of compound have furnished a variety of new structural elements, involving two directly bonded phosphorus atoms in two different oxidation states and / or coordination numbers. |
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