Exocyclic Substitution of Five-Membered Ring Chlorophosphates: A Reexamination of the rule For Nucleophilic Substitution at Phosphorus |
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| Authors: | R J P Corriu G F Lanneau D Leclercq |
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| Institution: | Laboratoire des Organométalliques, LA 349 , Université des Sciences et Techniques du Languedoc , 34060, Montpellier, France |
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| Abstract: | Abstract Opposite to the SN2(P) reactions taking place with inversion, which are highly dependent upon the nature of the nucleophile, exocyclic substitutions of five-membered ring chlorophosphates with retention show a marked kinetic levelling effect, emphasing silicon-type argumentations. |
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