ELECTRON-TRANSFER PROCESSES. PART 40. REACTION OF ALKYL RADICALS WITH DIPHENYLPHOSPHIDE ANION |
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| Authors: | Glen A Russell Rajive K Khanna |
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| Institution: | Department of Chemistry , Iowa State University , Ames, Iowa, 50011 |
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| Abstract: | Abstract The anion Ph2P? (K+, 18-crown-6) reacts with t-BuHgCl in HMPA to form Ph2PCMe3 by a free radical chain mechanism. In Me2SO, Ph2P(O)CMe3 is produced. Reaction of Ph2P? with PhCOCH2HgCl yields the oxidative dimerization product isolable from HMPA but readily converted to Ph2P(O)P(O)Ph2 in Me2SO. |
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