REACTIONS OF DITHIOLETHIONES WITH N,N-DICHLOROAMIDES |
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Authors: | Friedrich Boberg Gerhard-Jürgen Wentrup Udo Puttins |
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Institution: | Institute of Organic Chemistry, Technical University of Clausthal , D-3392, Clausthal-Zellerfeld, Germany |
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Abstract: | Abstract Dependent on the starting materials and the reaction conditions N,N-dichloroamides Cl2N-X (X = COaryl, CO2alkyl, SO2aryl, SO2N(alkyl)2) react with dithiolethiones 1 and 5 to N-(dithiolyliden)amides 2, 6, S-(dithiolylidene)sulfimides 3, thionoxides 7 and dithiolones 4, 8. The mechanisms have been studied. |
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