STUDY OF THE ALKALINE CLEAVAGE OF THE P[sbnd]C BOND IN PHOSPHINE OXIDES AND DERIVATIVES OF TRICHLOROMETHANEPHOSPHONATE |
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| Authors: | Gunnar Aksnes Roald Gierstae Erik A. Wulvik |
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| Affiliation: | Chemical Institute, University of Bergen , N-5007, Bergen, Norway |
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| Abstract: | Abstract A study of alkaline decomposition of several aromatic phosphine oxides containing p- and o-nitrobenzyl, and trichloromethyl as leaving groups, is reported. The property of the trichloromethyl group as leaving group, and the CCl? 3-group's further decomposition in the hydrolysis of diethyl and disodium trichloromethanephosphonates, have also been investigated. |
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