Synthesis and Reactivity of New Pentacoordinated Phosphoenolpyruvate Derivatives |
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| Authors: | Lydie Labaudiniere Yves Leroux Ramon Burgada |
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| Affiliation: | 1. Laboratoire de Chimie des Organo-éléments , tour 44-45 Université P. &2. M. Curie , 4 place Jussieu F-75252, Paris Cédex , 05 |
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| Abstract: | Abstract Pentaoxyphosphoranes are closely related as intermediates to the biologically important phosphate ester reactions. Thus, the hydrolysis of phosphoenolpyruvate 1, a strong phosphorylating agent, proceeds most probably via the formation of the cyclic acyloxyphosphorane 2. |
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