Pathways in the Nucleophilic Substitution Reactions of Halogenocyclophosphazenes and Subtle Aspects of the Mechanism of Formation of Bicyclic Phosphazenes |
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Authors: | P Y Narayana Swamy S Ganapathiappan K C Kumara Swamy S S Krishnamurthy |
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Institution: | Department of Inorganic and Physical , Chemistry Indian Institute of Science , Bangalore, 560012, INDIA |
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Abstract: | Abstract Both associative SN2(P)] and dissociative SN1(P) and E1CB] mechanisms have been established for the amination reactions of haloenocyclophosphazenes from synthetic and kinetic studies. Several intricate details concerning the formation of bicyclic phosphazenes have been unravelled. |
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