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Synergistic hybrid catalyst for cyclic carbonate synthesis: remarkable acceleration caused by immobilization of homogeneous catalyst on silica |
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| Authors: | Takahashi Toshikazu Watahiki Tsutomu Kitazume Shoji Yasuda Hiroyuki Sakakura Toshiyasu |
| Institution: | Research Institute for Innovation in Sustainable Chemistry, National Institute of Advanced Industrial Science and Technology (AIST), 1-1-1 Higashi, Tsukuba, Ibaraki 305-8565, Japan. |
| Abstract: | The catalytic activity of phosphonium salts towards cyclic carbonate synthesis from propylene oxide and CO2 has been enormously enhanced by their immobilization onto silica that itself has no catalytic activity. |
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