The [2,3]Wittig rearrangement of 2-alkenyloxyacetic acids and its applications to the stereocontrolled synthesis of β, γ-unsaturated aldehydes and conjugated dienoic acids |
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Authors: | Takeshi Nakai Kōichi Mikami Shiro Taya Yasuhiro Kimura Tetsuya Mimura |
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Institution: | Department of Chemical Technology, Tokyo Institute of Technology, Meguro-ku, Tokyo 152, Japan |
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Abstract: | Dianions generated from 2-alkenyloxyacetic acids readily undergo the 2,3]sigmatropic rearrangement uhich can constitute the versatile synthetic sequences for the stereocontrolled synthesis of β,γ-unsaturated aldehydes and conjugated dienoic acids. |
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