A novel chain reaction induced by cathodic reduction. Addition of trichloromethyl anion to aldehydes or vimyl acetate |
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| Authors: | Tatsuya Shono Hiroshi Ohmizu Souta Kawakami Shinji Nakano Naoki Kise |
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| Institution: | Department of Synthetic Chemistry, Faculty of Engineering, Kyoto University, Yoshida, Sakyo, Kyoto 606, Japan |
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| Abstract: | A novel chain reaction induced by cathodic reduction was found in the reaction system consisting of carbon tetrachloride, chloroform, and electrophiles such as aldehydes or vinyl acetate. The current efficiency of addition of trichloromethyl anion to electrophiles was extremely high. Synthesis of an analogue of ethyl chrysanthemate using this new reaction was also described. |
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