Epimeric 2-norbornyl cations in the solvolysis of 6-exo- and 6-endo-substituted 2-exo-norbornyl p-toluenesulfonates |
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| Authors: | Cyril A Grob Bettina Günther Reinhard Hanreich Adrian Waldner |
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| Institution: | Institute of Organic Chemistry, University of Basel, St. Johanns-Ring 19, CH-4056 Basel, Switzerland. |
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| Abstract: | Solvolysis of 6-exo- and 6-endo-substituted 2-exo-norbornyl tosylates and , respectively, yields identical or different product mixtures depending on the inductive effect of the substituent, indicating that induction involves graded σ-participation. |
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