Reactivity of singlet oxygen toward strained substrates and a novel non-photochemical method for determination of quenching constants of singlet oxygen. |
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Authors: | Nicholas J Turro Ming-Fea Chow Sheldon Kanfer Marcia Jacobs |
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Institution: | Department of Chemistry, Columbia University New York, New York 10027 USA |
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Abstract: | Rate constants for quenching of 1O2 by a number of strained molecules have been determined by the competitive rubrene photooxidation method; the rate constant for quenching by Q may be evaluated by adaption of a kinetic analysis already in the literature for the rubrene photooxidation method. |
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