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Reactivity of singlet oxygen toward strained substrates and a novel non-photochemical method for determination of quenching constants of singlet oxygen.
Authors:Nicholas J Turro  Ming-Fea Chow  Sheldon Kanfer  Marcia Jacobs
Institution:Department of Chemistry, Columbia University New York, New York 10027 USA
Abstract:Rate constants for quenching of 1O2 by a number of strained molecules have been determined by the competitive rubrene photooxidation method; the rate constant for quenching by Q may be evaluated by adaption of a kinetic analysis already in the literature for the rubrene photooxidation method.
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