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Thermal stability of perfluoroalkanesulfonic acids and their anhydrides. New and easy approach to RFSO2ORF esters.
Authors:MOudrhiri Hassani  A Germain  D Brunel  A Commeyras
Institution:Laboratoire de Chimie Organique, Université des Sciences et Techniques du Languedoc - 34060 - Montpellier Cédex. France
Abstract:Perfluoroalkanesulfonic anhydrides (RFSO2)2O when mixed with acids decompose into perfluoroalkanesulfonic esters RFSO2ORF, thereby providing a new facile synthesis of these esters from perfluoroalkanesulfonic acids and phosphorus pentoxide.
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