The reactions of phenolic reagents with α-bromo Michael acceptors in the K2CO3-acetone system. A stereospecific AdSNE process. |
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Authors: | Vittorio Rosnati Antonio Saba Aldo Salimbeni |
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Affiliation: | Istituto di Chimica Organica Via Muroni 25, 07100 Sassari, Italia;Istituto Lusofarmaco d''Italia, Via Carnia 20, 20132 Milano, Italia |
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Abstract: | α-bromo Michael acceptors undergo ipso-substitution by phenol or benzenethiol in the K2CO3-acetone system, the reaction originating the (Z) isomers, via a stereospecific AdSNE process. |
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