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Addition and cycloaddition reactions of allenyl cations with various cycloalka-1,3-dienes
Authors:Herbert Mayr  Franz Schütz
Institution:Institut fur Organische Chemie der Friedrich-Alexander-Universität Erlangen-Nürnberg, Henkestrasse 42, D-8520 Erlangen, Federal Republic of Germany
Abstract:Allenyl cations
, generated insitu from propargyl chlorides and zinc chloride give monocyclic adducts or 3+4] and 2+4] cycloaddition products with various cycloalka-1,3-dienes. The mode of addition depends on R and the ring size of the 1,3-dienes.
Keywords:
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