Institut fur Organische Chemie der Friedrich-Alexander-Universität Erlangen-Nürnberg, Henkestrasse 42, D-8520 Erlangen, Federal Republic of Germany
Abstract:
Allenyl cations , generated from propargyl chlorides and zinc chloride give monocyclic adducts or 3+4] and 2+4] cycloaddition products with various cycloalka-1,3-dienes. The mode of addition depends on R and the ring size of the 1,3-dienes.