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A novel ethylene-bridged spiro[3.2]Hexane
Authors:Louis A. Carpino  Peter Gund  James P. Springer  Tamara Gund
Affiliation:Department of Chemistry, University of Massachusetts, Amherst, MA 01003 USA;Merck Sharp and Dohme Research Laboratories, Rahway, N.J. 07065 USA;Rutgers The State University of New Jersey, New Brunswick, N.J. 08903 USA
Abstract:3,3-Dichlorotricyclo[5.1.0.01,4]oct-5-en-2-one (1) was prepared by addition of dichloroketene to 1,3-cyclohexadiene followed by allylic bromination and dehydrobromination.
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