A novel rearrangement of alkyl (n-alkylamido) methyl sulfides |
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| Authors: | Yasuo Kurebayashi Yoshiharu Ishikawa Yoshiyasu Terao Minoru Sekiya |
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| Institution: | Shizuoka College of Pharmacy, 2-2-1 Oshika, Shizuoka 422, Japan |
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| Abstract: | The finding of a new rearrangement of alkyl (N-alkylamido) methyl sulfides promoted by strong bases such as NaH, LDA, and t-BuLi is described. The reaction induces a migration of the alkyl group linked to the sulfur to the amide carbonyl giving the corresponding ketone. |
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