Vitesse des ultrasons dans les gaz rares sous haute pression a la temperature de 298.15 K

By a Pulse Echoes Overlap Method, the speed of ultra sound has been worked out at 15 MHz for the complete noble gas series at temperature 298.15 K in a very wide density range (which corresponds at pressures up to 10 kbar for light noble gases). When the molar density and the isothermal compressibility coefficient are known, the ratio of specific heats can be deduced as a function of density. In the case of argon the evolution of both c_p and c_v has been obtained separately and a value of 3R is determined before the fluid-solid transition. These thermodynamical quantities have been compared with those derived from the numerical equation of state of Hansen for a Lennard-Jones fluid. One notices good agreement between predictions and experimental results for hot gases.