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A chiral luminescent Au16 ring self-assembled from achiral components |
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| Authors: | Yu Shu-Yan Zhang Zhong-Xing Cheng Eddie Chung-Chin Li Yi-Zhi Yam Vivian Wing-Wah Huang Hai-Ping Zhang Rongben |
| Institution: | State Key Laboratory of Polymer Physics and Chemistry, Institute of Chemistry, The Chinese Academy of Sciences, Beijing 100080, People's Republic of China. syu@iccas.ac.cn |
| Abstract: | A luminescent supramolecular chiral Au16 ring with 4.822 nm perimeter that self-assembled from a tetrameric array of achiral Au2 units is described. Intra- and intermolecular Au...Au interactions play an important role in directing its chiral self-assembly. |
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