Hg(II)...Pd(II) metallophilic interactions |
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Authors: | Kim Mieock Taylor Thomas J Gabbaï François P |
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Institution: | Department of Chemistry, Texas A&M University, College Station, Texas 77843, USA. |
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Abstract: | Reaction of bis(pentafluorophenyl)mercury (1) with the Pd(II) complexes Pd(salophen)] (I, salophen = N,N'-disalicylidene-o-phenylenediaminate) and Pd(N--C)(OAc)]2 (II, N--C = (2-(2-pyridyl)phenyl-C,N)) leads to the formation of the supramolecular complexes 1-(I)2] and 1-(II)2] in which the mercury synthon is sandwiched by two molecules of the palladium complex. These complexes, whose formation can be observed in solution by UV-vis spectroscopy, have been fully characterized. The short Hg-Pd distances of 3.2841(2) A in 1-(I)2] and 3.1065(8) A in 1-(II)2] indicate the presence of a Hg-Pd metallophilic interaction which, at least for 1-(II)2], is complemented by a Pd(II)-->Hg(II) donor-or component. |
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