Comparison of traditional cloud-point extraction and on-line flow-injection cloud-point extraction with a chemiluminescence method using benzo[a]pyrene as a marker |
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Authors: | Guan Qun Song Chao Lu Kazuichi Hayakawa Jin-Ming Lin |
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Affiliation: | (1) State Key Laboratory of Environmental Chemistry and Ecotoxicology, Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences, P.O. Box 2871, Beijing, 100085, People’s Republic of China;(2) Graduate School of Natural Science and Technology, Faculty of Pharmaceutical Sciences, Kanazawa University, Kakuma-machi, Kanazawa 920-1192, Japan |
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Abstract: | In this work, using benzo(a)pyrene (BaP) as marker, the analytical merits of on-line flow-injection cloud-point extraction (FI CPE), including preconcentration factor, extraction efficiency, sample throughput, and analysis time were evaluated by use of peroxyoxalate chemiluminescence (CL) detection. Moreover, by detailed discussion of several preconcentration conditions for traditional and on-line FI CPE the advantages of on-line FI CPE became conspicuously apparent. When coupled with separation techniques such as high-performance liquid chromatography (HPLC) or capillary electrophoresis (CE), on-line FI CPE–CL has much potential for analysis of low concentrations of polycyclic aromatic hydrocarbons (PAH) in environmental samples. |
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Keywords: | On-line flow-injection cloud-point extraction Traditional cloud-point extraction Chemiluminescence Benzo(a)pyrene |
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