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| Hydrothermal Synthesis and Characterization of a Novel Two-dimensional Framework Materials Constructed from Polyoxometalate and Coordination Groups: [H_2Mo_(5.5)V_(10.5)O_(40)(PO_4)][Cu(en)_2]_4·7H_2O | |
| 作者姓名： | CUI Xiao-bing 1 ZHENG Shou-tian 1 SUN Yan-qiong 1 and YANG Guo-yu 1 2** 1. Coordination and Hydrothermal Chemistry Group State Key Laboratory of Structural Chemistry Fujian Institute of Research on the Structure of Matter Chinese Academy of Sciences Fuzhou 350002 P. R. China 2. State Key Laboratory of Coordination Chemistry Najing University Nanjing 210093 P. R. China |
| 作者单位： | CUI Xiao-bing 1，ZHENG Shou-tian 1，SUN Yan-qiong 1 and YANG Guo-yu 1，2** 1. Coordination and Hydrothermal Chemistry Group，State Key Laboratory of Structural Chemistry，Fujian Institute of Research on the Structure of Matter，Chinese Academy of Sciences，Fuzhou 350002，P. R. China; 2. State Key Laboratory of Coordination Chemistry，Najing University，Nanjing 210093，P. R. China |
| 基金项目： | SupportedbytheNationalNaturalScienceFoundationofChina(No .2 0 2 710 5 0and 2 0 1710 4 5 ) ,theMinistryofFinanceofChinaandtheTalentsProgramofChineseAcademyofSciences |
| 摘 要： | IntroductionPolyoxometalatesarewidelystudiedfortheirin terestingapplicationsincatalysis ,electronicconduc tivity ,magnetism ,nonlinearopticsandmedicine[1— 4 ] .Whilethemechanismofthesynthesisofpolyoxometalatesremainselusiveandisoftende scribedasself assembly ,thereseemstobeanincreas inguseofthecombinationofthehydrothermalmethodandthestructure directingtemplate .There searchwiththismethodhasdemonstratedthatanum beroftransitionmetaloxides ,typicallyreducedmolybdenumoxides ,mixedvalancevanadiumo… |
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