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Synthesis and structure of N-(2-silatranylethyl)pyrazoles
Authors:V. D. Sheludyakov  N. E. Kuz’mina  A. M. Abramkin  A. A. Korlyukov  D. E. Arkhipov  S. V. Loginov  D. A. Cheshkov  P. A. Storozhenko
Affiliation:1.State Research Institute of Chemistry and Technology of Organometallic Compounds,Moscow,Russia;2.Medical Equipment Scientific Appraisal Center,Moscow,Russia;3.Nesmeyanov Institute of Organometallic Compounds,Russian Academy of Sciences,Moscow,Russia
Abstract:Organosilicon pyrazole derivatives containing a 2-siltranylethyl fragment on the nitrogen atom were synthesized, and their structural and stereoelectronic parameters were determined by X-ray analysis and 1H, 13C, and 29Si NMR spectroscopy. The nature of interaction between the pyrazole and silatrane fragments was studied.
Keywords:
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