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Oxygen evolution on lead dioxide modified with fluorine and iron
Authors:A B Velichenko  D V Girenko  N V Nikolenko  R Amadelli  E A Baranova  F I Danilov
Institution:(1) Ukrainian State Chemical Technology University, pr. Gagarina 8, 320640 Dnepropetrovsk, Ukraine;(2) Center of Photochemistry and Catalysis, Ferrara University, via L Borsari 46, 1-44100 Ferrara, Italy
Abstract:In the oxygen evolution reaction in a sulfuric acid solution, the electrocatalytic activity of lead dioxide doped with fluorine or iron changes. At low and elevated dopant concentrations, the reaction rate is limited by the transfer of the second and first electrons, respectively. Dedicated to the ninetieth anniversary of Ya.M. Kolotyrkin’s birth.
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