1,4-Dihydro-1,4-diphosphinine fused with two tetrathiafulvalenes |
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| Authors: | Avarvari Narcis Fourmigué Marc |
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| Institution: | Laboratoire de Chimie, Ingénierie Moléculaire et Matériaux d'Angers, UMR 6200 CNRS-Universite d'Angers, UFR Sciences, Bat. K, 2 Bd. Lavoisier, 49045, Angers Cedex, France. narcis.avarvari@univ-angers.fr |
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| Abstract: | Electrochemical and theoretical investigations demonstrate through-bond interactions between two TTF moieties fused to a 1,4-dihydro-1,4-diphosphinine, for which the single crystal X-ray structure of the cis isomer is described together with that of a mixed-valent, charge-localized, radical cation salt with Mo6O19(2-), obtained upon electrocrystallization of the same cis isomer. |
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