Interactions in Cp2TiX-AlH3−nXn-Et2O(NEt3) systems |
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| Authors: | Boris M Bulychev Aleksandr L Kostenko Natal'ya A Yakovleva Grigorii L Soloveichik |
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| Institution: | (1) Department of Chemistry, Moscow State University, 117234 Moscow, USSR;(2) Institute of New Chemical Problems, Academy of Sciences of the USSR, 142432 Chernogolovka, USSR |
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| Abstract: | Summary Cp2TiX-AlH3–nXn-Et2O(NEt3) systems where X is Cl or Br, and n=0 or 1 have been studied by dielectrometric and calorimetric titration and by e.s.r. techniques. Bimetallic 1 1 compounds containing hydrogen bridges are formed in all systems. All reaction products, with the exception of Cp2TiH2AlHCl · Et2O formed at 20 to 25°, are monomeric in solution. The monochloro derivative is a dimer containing both ordinary and double hydrogen bridges. |
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