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Reaction of nitrosyltribromide with rhodium(I) complexes and with rhodiumtrichloride trihydrate,in the presence of triphenylphosphine and triphenylarsine
Authors:Krishna K. Pandey  Someswar Datta  Umesh Agarwala
Affiliation:(1) Department of Chemistry, Indian Institute of Technology, Kanpur, 208016, U.P., India
Abstract:Summary Nitrosyltribromide reacts with rhodium(I) complexes and with rhodiumtrichloride trihydrate in the presence of triphenylphosphine and triphenylarsine to give rhodium(III) nitrosyl complexes and rhodium(III) hyponitrite complexes which are characterized by i.r. spectra, magnetic measurements and by elemental analyses.
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