Molecular Precursors for the Phase‐Change Material Germanium‐Antimony‐Telluride,Ge2Sb2Te5 (GST) |
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Authors: | Nicole Harmgarth Florian Zörner Phil Liebing Edmund P. Burte Mindaugas Silinskas Felix Engelhardt Frank T. Edelmann |
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Affiliation: | 1. Chemisches Institut der Otto‐von‐Guericke‐Universit?t Magdeburg, Magdeburg, Germany;2. Laboratorium für Anorganische Chemie, ETH Zürich, Zürich, Switzerland;3. Institut für Mikro‐ und Sensorsysteme, Otto‐von‐Guericke‐Universit?t, Magdeburg, Germany;4. http://www.ich.ovgu.de/Lehrstühle/Anorganische+Chemie.html+49‐391‐67‐12933 |
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Abstract: | This review provides an overview of the precursor chemistry that has been developed around the phase‐change material germanium‐antimony‐telluride, Ge2Sb2Te5 (GST). Thin films of GST can be deposited by employing either chemical vapor deposition (CVD) or atomic layer deposition (ALD) techniques. In both cases, the success of the layer deposition crucially depends on the proper choice of suitable molecular precursors. Previously reported processes mainly relied on simple alkoxides, alkyls, amides and halides of germanium, antimony, and tellurium. More sophisticated precursor design provided a number of promising new aziridinides and guanidinates. |
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Keywords: | Germanium‐antimony‐telluride Germanium Antimony Tellurium Atomic layer deposition Chemical vapor deposition |
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