Synthesis,Characterization, and Fluorescence Chemosensor Properties of a cis‐Dioxomolybdenum(VI) Complex Containing Multidentate Hydrazone Ligands |
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| Authors: | Sunshine Dominic Kurbah Arvind Kumar Sankey Shangpung Ibanphylla Syiemlieh Iohboklang Khongjoh Ram Ashray Lal |
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| Institution: | 1. Centre for Advanced Studies, Department of Chemistry, North‐Eastern Hill University, Shillong, India;2. Department of Chemistry, Faculty of Science and Technology, The University of West‐Indies, St. Augustine, Trinidad and Tobago |
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| Abstract: | The homobimetallic molybdenum(VI) complex, (MoO2)2(slsch)(DMF)2], derived from multidentate hydrazone ligand (H4slsch = disalicylaldehyde succinoyldihydrazone) was synthesized. The complex was obtained by reaction of the ligand with Mo2(acac)2 in 1:2 molar ratio in methanol. It was characterized by using various spectroscopic techniques. The structure of the complex was established by single crystal X‐ray diffraction. The complex shows fluorescence emission, responds toward AlIII ions, and hence it can be used as fluorescence chemosensor for sensing AlIII ions. The sensing properties show that the complex is more efficient and sensitive towards AlIII ions than the rest of the ions used in the presented study. |
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| Keywords: | Bimetallic Crystal structure Fluorescence 1H NMR Molybdenum |
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