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Copper(I)-promoted synthesis of chloromethyl ketones from trichloromethyl carbinols |
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| Authors: | Ram Ram N Manoj T P |
| Affiliation: | Department of Chemistry, Indian Institute of Technology, Delhi, Hauz Khas, New Delhi-110016, India. rnram@chemistry.iitd.ernet.in |
| Abstract: | Reaction of several trichloromethyl carbinols with 2 equiv of CuCl/bpy in refluxing DCE for 3 h afforded chloromethyl ketones in excellent yield by 1,2-H shift in the copper-chlorocarbenoid intermediate. |
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