The inverted micellar catalysis of the reaction of 2-aminomethylphenols with 4-nitrophenyl bis(chloromethyl)phosphinate |
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| Authors: | E P Zhil'tsova L A Kudryavtseva R A Shagidullina |
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| Institution: | (1) A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan' Research Center of the Russian Academy of Sciences, 8 ul. Akad. Arbuzova, 420088 Kazan', Russian Federation |
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| Abstract: | The parameters of the reaction ofpara-substituted 2-aminomethylphenols with 4-nitrophenyl bis(chloromethyl)phosphinate in toluene catalyzed by reversed micelles
of polyethylene glycol-600 monolaurate depend on the nucleophile structure. The efficiency of the catalytic action increases
in the series of substitutes C9H19
i<H<Cl. An increase in the catalytic activity of micelles in the region of structural rearrangement of micelle aggregates was
observed.
Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 2, pp. 275–278, February, 1999. |
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| Keywords: | micellar catalysis micelle structure nonionic surfactant 2-aminomethylphenols |
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