The adsorption of polar molecules on the surface of graphite modified with a monomolecular layer of a mesogen |
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Authors: | S. Yu. Kudryashov |
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Affiliation: | (1) Department of Chemistry, State University of New York Binghamton, Binghamton, NY 13902-6016, USA |
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Abstract: | An equation for the potential energy of the interaction of a quasi-solid polar adsorbate molecule with a semiinfinite graphite crystal containing a monomolecular layer of polar anisometric particles on its surface was obtained. Adsorbate-modifier electrostatic interactions were considered in the dipole-dipole approximation. Dispersion interactions were described using the Lennard-Jones potentials (6, 12). The suggestion was made that a modifier monolayer impermeable to adsorbate molecules could be modeled by force centers that formed a two-dimensional translationally periodic lattice and by force centers uniformly distributed in a plane parallel to the outer face of graphite crystals. |
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