Electrochemical generation of c 60 2+ and c 60 3+ |
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Authors: | Bruno Carlo Doubitski Iouri Marcaccio Massimo Paolucci Francesco Paolucci Demis Zaopo Antonio |
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Institution: | Università di Bologna and INSTM, Dipartimento di Chimica "G. Ciamician", Via Selmi 2, 40126 Bologna, Italy. |
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Abstract: | The adoption of suitable experimental conditions, which comprise ultra-dry solvents and electrolytes with very high oxidation resistance and low nucleophilicity, has allowed observation, for the first time, of the cyclic voltammetric reversible generation of C602+ and C603+. The present study adds valuable information on the still relatively unknown properties of these important all-carbon carbocations and, in view of their very high reactivity, offers new possible routes for fullerene functionalization. |
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