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Michael condensation of 3-arylidene-3H-pyrrol-2-ones and 3-arylidene-3H-furan-2-ones with cyclohexanone
Authors:Z. Yu. Timofeeva  A. Yu. Yegorova
Affiliation:(1) N. G. Chernyshevskii Saratov State University, Saratov, 410012, Russia
Abstract:The Michael condensation in the series of 5-aryl-3-arylidene-3H-pyrrol-2-ones and 5-aryl-3-arylidene-3H-furan-2-ones, containing an activated C=C bond, with cyclohexanone was investigated. It was shown that the condensation products were 1,5-dicarbonyl compounds containing a heterocyclic fragment. The enolization of one of the oxo groups, leading to the formation of hydroxypyrrole or hydroxyfuran structures, was demonstrated by the spectral data. __________ Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 6, pp. 823–827, June, 2007.
Keywords:N-aryl-5-aryl-3-arylidene-3H-pyrrol-2-ones  N-unsubstituted 5-aryl-3-arylidene-3H-pyrrol-2-ones  5-aryl-3-arylidene-3H-furan-2-ones  cyclohexanone  acceptor  condensation
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