| 利用高压釜合成烷基咪唑碘及在太阳电池中的应用 |
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| 引用本文： | 王峰,葛茜,史成武.利用高压釜合成烷基咪唑碘及在太阳电池中的应用[J].阜阳师范学院学报(自然科学版),2008,25(3):41-44. |
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| 作者姓名： | 王峰 葛茜 史成武 |
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| 作者单位： | 1. 阜阳职业技术学院,化学系,安徽,阜阳236041
2. 合肥工业大学,化学系,安徽,合肥230009 |
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| 基金项目： | 国家重点基础研究发展计划项目(2006CB202600)资助 |
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| 摘 要： | 利用高压釜在无溶剂的条件下合成了离子液体1-甲基-3-丙基咪唑碘、1-甲基-3-己基咪唑碘.结果表明利用高压釜来提高反应温度,使1-甲基咪唑和碘代烷烃按化学计量比进行反应,产率近100%.该方法所得产品纯度高,操作简单无污染,实现了离子液体的绿色合成.另外,将这两种离子液体配制成电解质并组装成染料敏化太阳电池,测量了其光伏性能参数.
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| 关 键 词： | 1-甲基-3-己基咪唑碘 1-甲基-3-丙基咪唑碘 合成 染料敏化太阳电池 |
An Improved Preparation of 1,3-dialkyllimidazolium Iodide and Its Application in Dye Sensitized Solar Cells |
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| WANG Fang,GE Qian,SHI Cheng-wu.An Improved Preparation of 1,3-dialkyllimidazolium Iodide and Its Application in Dye Sensitized Solar Cells[J].Journal of Fuyang Teachers College:Natural Science,2008,25(3):41-44. |
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| Authors: | WANG Fang GE Qian SHI Cheng-wu |
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| Institution: | WANG Fang, GE Qian, SHI Cheng-wu (1. Fuyang Vocational-Technical Institute of Fuyang Anhui 236041; 2. School of Chemical Engineering, Hefei University of Technology, Hefei Anhui 230009 ,China) |
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| Abstract: | In this paper,we have reported an improved preparation of 1-methyl-3-propylimidazolium iodide and 3-hexyl-1-methylimidazolium iodide under solvent-free conditions by Teflon-lined,stainless autoclaves.It is shown that the resulting products are high pure,the conversion rate of 1-methylimidazole is close to 100 % and the procedure is simple and eco-friendly.The performance of dye sensitized solar cells with these ionic liquids are measured. |
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| Keywords: | 3-hexyl-1-methylimidazolium iodide 1-methyl-3-propylimidazolium iodide synthesis dye sensitized solar cell |
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