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静电离子色谱用于硼酸溶液中硼不同形态组分分离的研究
引用本文:申贵隽,彭增辉,黄海英,师宇华,于爱民,金钦汉. 静电离子色谱用于硼酸溶液中硼不同形态组分分离的研究[J]. 高等学校化学学报, 1999, 20(10): 1538-1541
作者姓名:申贵隽  彭增辉  黄海英  师宇华  于爱民  金钦汉
作者单位:吉林大学化学系, 长春 130023
摘    要:改进了把胆汁酸诱导体胶束(CHAPSO)涂覆在ODS载体上制备静电离子色谱固定相的方法.以纯水为流动相,采用示差折光检测器,研究了硼酸溶液中硼的形态、分离条件,并对色谱峰进行了解析.此外,还对硼酸溶液中硼离子、硼分子的色谱保留行为进行了探讨.

关 键 词:静电离子色谱    硼酸溶液  形态  保留行为  
收稿时间:1999-02-05

Studies on Separation of Different Species Containing Boron in Boric Acid Solution Using Electrostatic Ion Chromatography
SHEN Gui-Jun,PENG Zeng-Hui,HUANG Hai-ying,SHI Yu-hua,YU Ai-min,JIN Qin-Han. Studies on Separation of Different Species Containing Boron in Boric Acid Solution Using Electrostatic Ion Chromatography[J]. Chemical Research In Chinese Universities, 1999, 20(10): 1538-1541
Authors:SHEN Gui-Jun  PENG Zeng-Hui  HUANG Hai-ying  SHI Yu-hua  YU Ai-min  JIN Qin-Han
Affiliation:Department of Chemistry, Jilin University, Changchun 130023, China
Abstract:A stationary phase for the electrostatic ion chromatography(EIC) was improved by coating the reversed phase ODS column with conjugated bile acid salt micelles(CHAPSO). The detector of refactometry was connected on line to the EIC. Using pure water as mobile phase, the separation and speciation conditions of species in boric acid solution were studied. Retention behavior of EIC for ions and molecules in boric acid solutions were discussed.
Keywords:Electrostatic ion chromatography   Boron   Boric acid solution   Speciation   Retention behavior
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