Methyl Trifluoropyruvate Diethoxyphosphorylimine |
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| Authors: | Onys'ko P P Rassukanaya Yu V Sinitsa A D |
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| Institution: | (1) Institute of Organic Chemistry, National Academy of Sciences of Ukraine, Kiev, Ukraine |
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| Abstract: | The first example of trifluoropyruvate phosphorylimines was prepared, and its capability for O- and S-amidoalkylation of water, alcohols, and compounds with the SH function was shown. Phenol and 4-methoxyphenol are O-alkylated, while 3-dimethylaminophenol and indole undergo regiospecific C-alkylation at the site of the highest  -electron density. |
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