Isolation and characterization of stable, distinctly bent, trans-chelated bisphosphine palladium(0) species |
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| Authors: | Schnetz Thomas Röder Marc Rominger Frank Hofmann Peter |
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| Affiliation: | Organisch-Chemisches Institut der Universit?t Heidelberg, Im Neuenheimer Feld 270, D-69120 Heidelberg, Germany. |
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| Abstract: | The novel ligands and (i-Pr-Rucaphos, Cy-Rucaphos) react with (tmeda)PdMe(2) yielding ethane and distinctly bent, trans-spanning bisphosphine chelated 14-electron palladium(0) species, which have been fully characterized, including single crystal X-ray diffraction. |
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