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Correlation between the double-double effect and the contribution from covalency to bonding
Authors:S. Siekierski
Affiliation:(1) Department of Radiochemistry, Institute of Nuclear Research, 03-195 Warsaw, Poland
Abstract:The magnitude of the double-double /tetrad/ effect in unit cell volumes has been determined for a number of simple lanthanide compounds of the LnmXn type. The effect increases with decreasing electronegativity of the X atom, which indicates that the effect originates in the partially covalent character of the Ln-X bond.
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