Correlation between the double-double effect and the contribution from covalency to bonding |
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Authors: | S. Siekierski |
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Affiliation: | (1) Department of Radiochemistry, Institute of Nuclear Research, 03-195 Warsaw, Poland |
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Abstract: | The magnitude of the double-double /tetrad/ effect in unit cell volumes has been determined for a number of simple lanthanide compounds of the LnmXn type. The effect increases with decreasing electronegativity of the X atom, which indicates that the effect originates in the partially covalent character of the Ln-X bond. |
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