The formation of nalidixic acid dimers and excimers in aqueous solutions |
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Authors: | A V Polishchuk E T Karaseva T B Emelina V E Karasev |
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Institution: | (1) Institute of Chemistry, Far East Division, Russian Academy of Sciences, pr. Stoletiya Vladivostoka 159, Vladivostok, 690022, Russia |
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Abstract: | The influence of optical excitation on the formation of nalidixic acid dimers and excimers in aqueous media in the ground and excited states was studied. Quantum-chemical calculations of the total energy of monomers and dimers were performed. The spectral-luminescent characteristics of pairs of nlqH molecules were measured, and changes in charges on atoms in the ground and excited states were estimated. |
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