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SURFACE MODIFICATION OF POLYPROPYLENE MICROPOROUS MEMBRANES BY THE ADSORPTION OF NON-IONIC SURFACTANTS
作者姓名:Ya-jie  Xie  Hai-yin  Yu  Zhi-kang  Xu
作者单位:[1]College of Biological & Chemical Engineering, Jiaxing University, Jiaxing 314001, China [2]Instltute of Polymer Science, Zhejiang University, and Key Laboratory of Macromolecule Synthesis and Functionalization (Zhejiang University), Ministry of Education, Hangzhou 310027, China
基金项目:国家高技术研究发展计划(863计划) , 浙江省嘉兴市资助项目
摘    要:Surface modification by physical adsorption of a series of non-ionic surfactants including Tween 20, Tween 40, Tween 60, Tween 80 and Tween 85, was accomplished on polypropylene microporous hollow fiber and flat membranes. The adsorption curve of the membrane surface was analyzed by weight measurements and the typical results showed a twoplatform character similarly. Differences in the degree and curve shape of adsorption resulting from such factors as concentration, temperature, as well as water cleaning time were observed for Tween 85 among other Tweens. Attenuated total reflection - Fourier transform infrared spectroscopy analysis and field emission scanning electron microscopy observation showed that the adsorption of Tween on polypropylene microporous membrane (PPMM) is effective and occurs mainly in the pores of PPMMs at low adsorption amount, and on the membrane surface also at high adsorption value.

关 键 词:聚丙烯微孔膜  表面改性  非离子表面活性剂  吸附
收稿时间:2005-09-20
修稿时间:2006-01-16

SURFACE MODIFICATION OF POLYPROPYLENE MICROPOROUS MEMBRANES BY THE ADSORPTION OF NON-IONIC SURFACTANTS
Ya-jie Xie Hai-yin Yu Zhi-kang Xu.SURFACE MODIFICATION OF POLYPROPYLENE MICROPOROUS MEMBRANES BY THE ADSORPTION OF NON-IONIC SURFACTANTS[J].Chinese Journal of Polymer Science,2006,0(4):421-429.
Authors:Ya-jie Xie  Hai-yin Yu  Zhi-kang Xu
Institution:Zhejiang University
Abstract:Surface modification by physical adsorption of a series of non-ionic surfactants including Tween 20, Tween 40,Tween 60, Tween 80 and Tween 85, was accomplished on polypropylene microporous hollow fiber and flat membranes. The adsorption curve of the membrane surface was analyzed by weight measurements and the typical results showed a twoplatform character similarly. Differences in the degree and curve shape of adsorption resulting from such factors as concentration, temperature, as well as water cleaning time were observed for Tween 85 among other Tweens. Attenuated total reflection - Fourier transform infrared spectroscopy analysis and field emission scanning electron microscopy observation showed that the adsorption of Tween on polypropylene microporous membrane (PPMM) is effective and occurs mainly in the pores of PPMMs at low adsorption amount, and on the membrane surface also at high adsorption value.
Keywords:Polypropylene microporous membranes  Surface modification  Adsorption  Surfactants  Tween
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